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Potassium octachlorodimolybdate
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Potassium octachlorodimolybdate : ウィキペディア英語版
Potassium octachlorodimolybdate

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Potassium octachlorodimolybdate (systematically named potassium bis(tetrachloridomolybdate)(''Mo''—''Mo'')(4−)) is an inorganic compound with the chemical formula (also written as ). It is known as a red-coloured, microcrystalline solid. The anion is of historic interest as one of the earliest illustrations of a quadruple bonding. The salt is usually obtained as the pink-coloured dihydrate.
The compound is prepared in two steps from molybdenum hexacarbonyl:
:2 Mo(CO)6 + 4 HO2CCH3 → Mo2(O2CCH3)4 + 2 H2 + 12 CO
:Mo2(O2CCH3)4 + 4 HCl + 4 KCl → K4Mo2Cl8 + 4 HO2CCH3
The reaction of the acetate with HCl was first described as providing trimolybdenum compounds, but subsequent crystallographic analysis confirmed that the product contains the ion with D4h symmetry. The Mo—Mo distance is 2.14 Å.
==References==



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